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Abstract:
A generalized synthesis of high-quality,
mesoporous zeolite (e.g., MFI-type) nanocrystals is
presented, based on a biomass-derived, monolithic Ndoped
carbonaceous template. As an example, ZSM-5
single crystals with desirable large-diameter (12−16 nm)
intracrystalline mesopores are synthesized. The platform
provides scope to optimize template dimensions and
chemistry for the synthesis of a range of micro-/
mesoporous crystalline zeolites in a cost-effective and
highly flexible manner.